http://www.youtube.com/watch?v=jS4NprloB-0
check out this tone. It sounds like a pretty cranked metal panel. Even in this low quality youtube clip you can hear that upper end chime and clang. It is very hard to get both the overdrive that this tone has while keeping the clean upper chime. You should hear this tone on a decent turntable with original vinyl ! yes it's two different guitar tracks, and likely two different amps but you can get a blend of it into one amp if you set out to do so.
tone check list:
chopped off bass - check
smooth overdriven mids - check
upper end chime and clang - check
minimal preamp distortion - check
Now imagine this tone but with the presence and bass cranked (which I don't believe he had), and you have the exact tone for unchained.
btw, for anyone interested in getting this tone, I can offer a few tips since this is my basic tone and is the sound of a SL which has been dialed in to chime while dimed and this is what it sounds like when you back it off back down to medium tone levels and maybe 7 on teh volume. Some tips. When I say the bass knob is cranked, it's not that the end tone is bassy. Contrary, you want to set up the amp so that even when the bass knob is jacked the end tone has no bass. It can be done by tube and compoment value choices and speaker choice. You want a worn out celestion m25. The older the better but you can use modern recreations. But if it has the modern extra doping i'd suggest you disolve some or most of it off. This loosens up the tone and decreases bass response.
The reason it's good to be able to use the bass knob instead of leaving it at 0 is because the 2 stage plexi really needs all teh gain it can get in order to get into ed territory and a bass knob on 0 is not only cutting bass it's cutting gain. So when you set up your amp while teh bass knob is at 10, you can then hang onto that gain but still get a tone with no bass. And all these old classic tones, including ed's, had absolutely zero bass. Cranking teh amp also cuts bass just by the nature of saturating teh transformers I believe so besides speaker and component choices, cranking the amp helps cut bass.